You should be listening to Adam Buxton's new Sunday lunchtime show on the apparently doomed 6 Music. I listened to the Podcast of the first episode, which had as a guest Julian Barratt of The Might Boosh fame.
The show is, as the title suggests, a music show which plays songs and sounds centered around a weekly theme. Saturday's broadcast, which can be listened to again here for the next couple of days, was constructed around mainstream experimentalism and featured a wonderful tracklist.
I am intrigued by the title of next weeks show: Toddler Tunes.